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Journal Articles

Valence state in Ce-based heavy fermion compounds at high magnetic fields

Matsuda, Yasuhiro*; Her, J.-L.*; Michimura, Shinji*; Inami, Toshiya; Ebihara, Takao*; Amitsuka, Hiroshi*

JPS Conference Proceedings (Internet), 3, p.011044_1 - 011044_6, 2014/06

Synchrotron X-ray absorption spectroscopy of CeRh$$_2$$Si$$_2$$ has been performed in pulsed high magnetic fields of up to 32 T. The Ce valence is slightly larger than 3+ at 5 K and decreases with increasing magnetic above 20 T. The field-induced valence change seems to correspond to the metamagnetic transition in the magnetization process. This phenomena is similar to our previous result on CeRu$$_2$$Si$$_2$$ and seems to be common in Ce-based heavy fermion compounds.

Journal Articles

Synchrotron X-ray spectroscopy study on the valence state in $$alpha$$- and $$beta$$-TbAlB$$_4$$ at low temperature and high magnetic fields

Matsuda, Yasuhiro*; Nakamura, Toshiyuki*; Kuga, Kentaro*; Nakatsuji, Satoru*; Michimura, Shinji*; Inami, Toshiya; Kawamura, Naomi*; Mizumaki, Masaichiro*

Journal of the Korean Physical Society, 62(12), p.1778 - 1781, 2013/06

 Times Cited Count:10 Percentile:55.85(Physics, Multidisciplinary)

The valence state of Yb ions in $$alpha$$- and $$beta$$-YbAlB$$_4$$ has been investigated by X-ray absorption and emission spectroscopy at temperatures from 2 to 280 K. It is found that the valence gradually increases with increasing temperature toward 3+ and that the characteristic temperature of the valence fluctuations is about 290 K. We also observe a small increase in the Yb valence ($$sim$$ 0.002) in $$beta$$-YbAlB$$_4$$ by a magnetic field of 32 T at 40 K.

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